无需循环：

print(a)
[[ 0.93230948         nan  0.47773439  0.76998063]
 [ 0.94460779  0.87882456  0.79615838  0.56282885]
 [ 0.94272934  0.48615268  0.06196785         nan]
 [ 0.64940216  0.74414127         nan         nan]]

#Obtain mean of columns as you need, nanmean is convenient.
col_mean = np.nanmean(a, axis=0)
print(col_mean)
[ 0.86726219  0.7030395   0.44528687  0.66640474]

#Find indices that you need to replace
inds = np.where(np.isnan(a))

#Place column means in the indices. Align the arrays using take
a[inds] = np.take(col_mean, inds[1])

print(a)
[[ 0.93230948  0.7030395   0.47773439  0.76998063]
 [ 0.94460779  0.87882456  0.79615838  0.56282885]
 [ 0.94272934  0.48615268  0.06196785  0.66640474]
 [ 0.64940216  0.74414127  0.44528687  0.66640474]]