虽然我不确定你想要完成什么，但这段代码对我有用。

<select id="mySelect" multiple="multiple">
  <option value="1">First</option>
  <option value="2">Second</option>
  <option value="3">Third</option>
  <option value="4">Fourth</option>
</select>

<script type="text/javascript"> 
$(document).ready(function() {
  if (!$("#mySelect option:selected").length) {
    $("#mySelect option[value='3']").attr('selected', 'selected');
  }
});
</script>