使用此代码…

    dt = city.GetAllCity();//your datatable
    string attachment = "attachment; filename=city.xls";
    Response.ClearContent();
    Response.AddHeader("content-disposition", attachment);
    Response.ContentType = "application/vnd.ms-excel";
    string tab = "";
    foreach (DataColumn dc in dt.Columns)
    {
        Response.Write(tab + dc.ColumnName);
        tab = "\t";
    }
    Response.Write("\n");
    int i;
    foreach (DataRow dr in dt.Rows)
    {
        tab = "";
        for (i = 0; i < dt.Columns.Count; i++)
        {
            Response.Write(tab + dr[i].ToString());
            tab = "\t";
        }
        Response.Write("\n");
    }
    Response.End();