您的课程应如下所示

[XmlRoot("StepList")]
public class StepList
{
    [XmlElement("Step")]
    public List<Step> Steps { get; set; }
}

public class Step
{
    [XmlElement("Name")]
    public string Name { get; set; }
    [XmlElement("Desc")]
    public string Desc { get; set; }
}

这是我的测试代码。

string testData = @"<StepList>
                        <Step>
                            <Name>Name1</Name>
                            <Desc>Desc1</Desc>
                        </Step>
                        <Step>
                            <Name>Name2</Name>
                            <Desc>Desc2</Desc>
                        </Step>
                    </StepList>";

XmlSerializer serializer = new XmlSerializer(typeof(StepList));
using (TextReader reader = new StringReader(testData))
{
    StepList result = (StepList) serializer.Deserialize(reader);
}

如果要读取文本文件，则应将文件加载到FileStream中并反序列化。

using (FileStream fileStream = new FileStream("<PathToYourFile>", FileMode.Open)) 
{
    StepList result = (StepList) serializer.Deserialize(fileStream);
}