这是我最后的工作代码。我的Web服务需要一个文件（POST参数名称为“ file”）和一个字符串值（POST参数名称为“ userid”）。

/// <summary>
/// Occurs when upload backup application bar button is clicked. Author : Farhan Ghumra
 /// </summary>
private async void btnUploadBackup_Click(object sender, EventArgs e)
{
    var dbFile = await ApplicationData.Current.LocalFolder.GetFileAsync(Util.DBNAME);
    var fileBytes = await GetBytesAsync(dbFile);
    var Params = new Dictionary<string, string> { { "userid", "9" } };
    UploadFilesToServer(new Uri(Util.UPLOAD_BACKUP), Params, Path.GetFileName(dbFile.Path), "application/octet-stream", fileBytes);
}

/// <summary>
/// Creates HTTP POST request & uploads database to server. Author : Farhan Ghumra
/// </summary>
private void UploadFilesToServer(Uri uri, Dictionary<string, string> data, string fileName, string fileContentType, byte[] fileData)
{
    string boundary = "----------" + DateTime.Now.Ticks.ToString("x");
    HttpWebRequest httpWebRequest = (HttpWebRequest)WebRequest.Create(uri);
    httpWebRequest.ContentType = "multipart/form-data; boundary=" + boundary;
    httpWebRequest.Method = "POST";
    httpWebRequest.BeginGetRequestStream((result) =>
    {
        try
        {
            HttpWebRequest request = (HttpWebRequest)result.AsyncState;
            using (Stream requestStream = request.EndGetRequestStream(result))
            {
                WriteMultipartForm(requestStream, boundary, data, fileName, fileContentType, fileData);
            }
            request.BeginGetResponse(a =>
            {
                try
                {
                    var response = request.EndGetResponse(a);
                    var responseStream = response.GetResponseStream();
                    using (var sr = new StreamReader(responseStream))
                    {
                        using (StreamReader streamReader = new StreamReader(response.GetResponseStream()))
                        {
                            string responseString = streamReader.ReadToEnd();
                            //responseString is depend upon your web service.
                            if (responseString == "Success")
                            {
                                MessageBox.Show("Backup stored successfully on server.");
                            }
                            else
                            {
                                MessageBox.Show("Error occurred while uploading backup on server.");
                            } 
                        }
                    }
                }
                catch (Exception)
                {

                }
            }, null);
        }
        catch (Exception)
        {

        }
    }, httpWebRequest);
}

/// <summary>
/// Writes multi part HTTP POST request. Author : Farhan Ghumra
/// </summary>
private void WriteMultipartForm(Stream s, string boundary, Dictionary<string, string> data, string fileName, string fileContentType, byte[] fileData)
{
    /// The first boundary
    byte[] boundarybytes = Encoding.UTF8.GetBytes("--" + boundary + "\r\n");
    /// the last boundary.
    byte[] trailer = Encoding.UTF8.GetBytes("\r\n--" + boundary + "--\r\n");
    /// the form data, properly formatted
    string formdataTemplate = "Content-Dis-data; name=\"{0}\"\r\n\r\n{1}";
    /// the form-data file upload, properly formatted
    string fileheaderTemplate = "Content-Dis-data; name=\"{0}\"; filename=\"{1}\";\r\nContent-Type: {2}\r\n\r\n";

    /// Added to track if we need a CRLF or not.
    bool bNeedsCRLF = false;

    if (data != null)
    {
        foreach (string key in data.Keys)
        {
            /// if we need to drop a CRLF, do that.
            if (bNeedsCRLF)
                WriteToStream(s, "\r\n");

            /// Write the boundary.
            WriteToStream(s, boundarybytes);

            /// Write the key.
            WriteToStream(s, string.Format(formdataTemplate, key, data[key]));
            bNeedsCRLF = true;
        }
    }

    /// If we don't have keys, we don't need a crlf.
    if (bNeedsCRLF)
        WriteToStream(s, "\r\n");

    WriteToStream(s, boundarybytes);
    WriteToStream(s, string.Format(fileheaderTemplate, "file", fileName, fileContentType));
    /// Write the file data to the stream.
    WriteToStream(s, fileData);
    WriteToStream(s, trailer);
}

/// <summary>
/// Writes string to stream. Author : Farhan Ghumra
/// </summary>
private void WriteToStream(Stream s, string txt)
{
    byte[] bytes = Encoding.UTF8.GetBytes(txt);
    s.Write(bytes, 0, bytes.Length);
}

/// <summary>
/// Writes byte array to stream. Author : Farhan Ghumra
/// </summary>
private void WriteToStream(Stream s, byte[] bytes)
{
    s.Write(bytes, 0, bytes.Length);
}

/// <summary>
/// Returns byte array from StorageFile. Author : Farhan Ghumra
/// </summary>
private async Task<byte[]> GetBytesAsync(StorageFile file)
{
    byte[] fileBytes = null;
    using (var stream = await file.OpenReadAsync())
    {
        fileBytes = new byte[stream.Size];
        using (var reader = new DataReader(stream))
        {
            await reader.LoadAsync((uint)stream.Size);
            reader.ReadBytes(fileBytes);
        }
    }

    return fileBytes;
}

我非常感谢达琳·卢梭（Darin
Rousseau）的帮助。