以下对我有用。参数量应在[0，100]范围内。当心，没有错误处理！

void SetAlsaMasterVolume(long volume)
{
    long min, max;
    snd_mixer_t *handle;
    snd_mixer_selem_id_t *sid;
    const char *card = "default";
    const char *selem_name = "Master";

    snd_mixer_open(&handle, 0);
    snd_mixer_attach(handle, card);
    snd_mixer_selem_register(handle, NULL, NULL);
    snd_mixer_load(handle);

    snd_mixer_selem_id_alloca(&sid);
    snd_mixer_selem_id_set_index(sid, 0);
    snd_mixer_selem_id_set_name(sid, selem_name);
    snd_mixer_elem_t* elem = snd_mixer_find_selem(handle, sid);

    snd_mixer_selem_get_playback_volume_range(elem, &min, &max);
    snd_mixer_selem_set_playback_volume_all(elem, volume * max / 100);

    snd_mixer_close(handle);
}