该代码对我有用：

using System;
using System.Collections.Generic;
using System.Linq;
using System.Text;
using System.Web.Script.Serialization;

namespace Json
{
    class Program
    {
        static void Main(string[] args)
        {
            Console.WriteLine(DeserializeNames());
            Console.ReadLine();
        }

        public static string DeserializeNames()
        {
            var jsonData = "{\"name\":[{\"last\":\"Smith\"},{\"last\":\"Doe\"}]}";

            JavaScriptSerializer ser = new JavaScriptSerializer();

            nameList myNames = ser.Deserialize<nameList>(jsonData);

            return ser.Serialize(myNames);
        }

        //Class descriptions

        public class name
        {
            public string last { get; set; }
        }

        public class nameList
        {
            public List<name> name { get; set; }
        }
    }
}