解决我的问题的方法是使用Rici建议的状态机增强Wikipedia上发布的算法。我在这里发布伪代码，因为它可能对其他人有用。

Support two states, ExpectOperand and ExpectOperator.

Set State to ExpectOperand
While there are tokens to read:
    If token is a constant (number)
        Error if state is not ExpectOperand.
        Push token to output queue.
        Set state to ExpectOperator.
    If token is a variable.
        Error if state is not ExpectOperand.
        Push token to output queue.
        Set state to ExpectOperator.
    If token is an argument separator (a comma).
        Error if state is not ExpectOperator.
        Until the top of the operator stack is a left parenthesis  (don't pop the left parenthesis).
            Push the top token of the stack to the output queue.
            If no left parenthesis is encountered then error.  Either the separator was misplaced or the parentheses were mismatched.
        Set state to ExpectOperand.
    If token is a unary operator.
        Error if the state is not ExpectOperand.
        Push the token to the operator stack.
        Set the state to ExpectOperand.
    If the token is a binary operator.
        Error if the state is not ExpectOperator.
        While there is an operator token at the top of the operator stack and either the current token is left-associative and of lower then or equal precedence to the operator on the stack, or the current token is right associative and of lower precedence than the operator on the stack.
            Pop the operator from the operator stack and push it onto the output queue.
        Push the current operator onto the operator stack.
        Set the state to ExpectOperand. 
    If the token is a Function.
        Error if the state is not ExpectOperand.  
        Push the token onto the operator stack.
        Set the state to ExpectOperand.
    If the token is a open parentheses.
        Error if the state is not ExpectOperand.
        Push the token onto the operator stack.
        Set the state to ExpectOperand.
    If the token is a close parentheses.
         Error if the state is not ExpectOperator.
         Until the token at the top of the operator stack is a left parenthesis.
             Pop the token off of the operator stack and push it onto the output queue.
         Pop the left parenthesis off of the operator stack and discard.
         If the token at the top of the operator stack is a function then pop it and push it onto the output queue.
         Set the state to ExpectOperator.
At this point you have processed all the input tokens.
While there are tokens on the operator stack.
    Pop the next token from the operator stack and push it onto the output queue.
    If a parenthesis is encountered then error.  There are mismatched parenthesis.

通过查看先前的标记，您可以轻松地区分一元运算符和二进制运算符（我是专门讲负前缀和减法运算符）。如果没有先前的标记，先前的标记是开括号，或者先前的标记是运算符，则您遇到了一元前缀运算符，否则遇到了二进制运算符。